Sangam: A Confluence of Knowledge Streams

Absolute coverage measurements of ultrathin alkali-metal films on reconstructed silicon

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dc.contributor Physics
dc.creator Banerjee, Rajarshi
dc.date 2016-06-27T19:03:18Z
dc.date 2016-06-27T19:03:18Z
dc.date 2001
dc.date.accessioned 2023-03-03T07:26:59Z
dc.date.available 2023-03-03T07:26:59Z
dc.identifier eprint:260
dc.identifier http://hdl.handle.net/10919/71500
dc.identifier.uri http://localhost:8080/xmlui/handle/CUHPOERS/281962
dc.description Metal/semiconductor interfaces, particularly those involving Si, are of great technological and scientific interest. In atomically abrupt interfaces, many properties are determined by interatomic interactions over a few layers, i.e., over ~1 nanometer. The initial stages of growth of an atomic layer related to structural and electronic properties are thus important to thin film behavior. Surface science studies on metal-semiconductor systems often lead to contradictory conclusions regarding bonding sites and even whether the first layer is metallic or not. A key piece of information that must be consistent with any study is the number of atoms per unit area in the first layer, which is difficult to assess directly. Alkali-metal-semiconductor systems have been studied as model abrupt interfaces for several years. Novel effects, such as electron localization, were observed. Still, determinations of absolute coverage have been lacking. This dissertation describes results of absolute coverage measurements for Cs on Si(100)(2X1), Si(111)(7X7), and Si (111)(v3 X v3)R30°-B reconstructed surfaces using Rutherford Backscattering Spectrometry in ultrahigh vacuum. The results bracket possible structural models for these systems. For the Cs/Si(111)(v3 X v3)R30°-B interface, this work confirms conclusions regarding electron localization effects and introduces considerations of ion-beam-induced desorption for the weakly-bound Cs
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dc.language en
dc.rights In Copyright
dc.rights http://rightsstatements.org/vocab/InC/1.0/
dc.subject reconstruction
dc.subject silicon
dc.subject thin films
dc.subject RBS
dc.subject interface
dc.subject surface physics
dc.subject alkali metals
dc.subject cesium
dc.subject ordered
dc.subject ordered growth
dc.subject epitaxy
dc.subject ion scattering
dc.subject semiconductors
dc.subject metalization
dc.subject characterization
dc.subject Rutherford
dc.subject boronated
dc.subject doped
dc.subject QC
dc.title Absolute coverage measurements of ultrathin alkali-metal films on reconstructed silicon
dc.type Dissertation


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